Joseph G Holehouse from Galena, OH, age 66

Thermoset Polymer Compositions
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US Patent:

47711027, Sep 13, 1988
Filed:

Aug 5, 1987
Appl. No.:

7/081939
Inventors:

Anil B. Goel - Worthington OH
Timothy A. Tufts - Columbus OH
Joseph G. Holehouse - Columbus OH
Assignee:

Ashland Oil, Inc. - Russell KY
International Classification:

C08L 6706
US Classification:

525 28
Abstract:

Thermoset polymers are prepared by reacting an ethylenically unsaturated resin monomer and a bicyclic amide acetal with a polyisocyanate in the absence or presence of a vinyl monomer. Reaction rates are suitable for effecting RIM processing. The resultant polymers exhibit improved impact resistance. Further variation in physical properties can be achieved through the use of a diol chain extender for the polyisocyanate.

High Performance Induction Curable Two-Component Structural Adhesive With Nonsagging Behavior
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US Patent:

47628642, Aug 9, 1988
Filed:

Jun 19, 1986
Appl. No.:

6/876060
Inventors:

Anil B. Goel - Worthington OH
Joseph G. Holehouse - Columbus OH
Jeffrey P. Jones - Columbus OH
Teresa DeLong - Marysville OH
Assignee:

Ashland Oil Inc. - Ashland KY
International Classification:

C08K 322
C08K 308
C08L 1300
C08L 6300
US Classification:

523428
Abstract:

An adhesive composition which is curable by electromagnetic induction heating when it is applied to various substrates, said adhesive comprising a mixture of (I) An epoxy resin component and (II) A hardener component and (III) From 2 to 60% by weight of (I) and (II) of an electromagnetic energy absorbing material is described.

Preparation Of Menthane Diisocyanate By Addition Of Isocyanic Acid To Terpinyl Monoisocyanates
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US Patent:

46187073, Oct 21, 1986
Filed:

Nov 25, 1985
Appl. No.:

6/801443
Inventors:

Robert A. Grimm - Columbus OH
Jai H. Kyung - Dublin OH
Phyllis L. Brusky - Columbus OH
Joseph G. Holehouse - Columbus OH
Biau-hung Chang - Worthington OH
Assignee:

Ashland Oil, Inc. - Ashland KY
International Classification:

C07C 7100
US Classification:

560337
Abstract:

A process for preparing menthane diisocyanate by reaction of a terpinyl monoisocyanate with isocyanic acid in a medium which is an excess of isocyanic acid, a polar solvent, or a mixture of solvents which includes a polar solvent in the presence of a catalyst which is a Bronsted acid or a Lewis acid is disclosed.

Production Of Isocyanic Acid
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US Patent:

43729339, Feb 8, 1983
Filed:

Apr 29, 1982
Appl. No.:

6/373085
Inventors:

Jai H. Kyung - Dublin OH
Joseph G. Holehouse - Columbus OH
Assignee:

Ashland Oil, Inc. - Ashland KY
International Classification:

C01C 300
C01C 314
US Classification:

423365
Abstract:

Isocyanic acid is formed directly from nitric oxide, carbon monoxide and hydrogen by contacting a supported iridium or rhodium metal catalyst at an elevated temperature with a feed stream of said reactants.

Polyurethane Pressure Sensitive Adhesives For Bonding Layered Structures
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US Patent:

46264752, Dec 2, 1986
Filed:

Sep 18, 1985
Appl. No.:

6/777111
Inventors:

Anil Goel - Worthington OH
Joseph Holehouse - Columbus OH
Kenneth Barnett - Worthington OH
Assignee:

Ashland Oil, Inc. - Ashland KY
International Classification:

B32B 2700
C08L 2300
C08G 1828
C08G 1877
US Classification:

4284231
Abstract:

A process for the production of a pressure sensitive adhesive comprising the interaction of a high molecular weight polyol, a polyisocyanate and a small amount of a bicyclic amide acetal wherein the process results in significant improvement in physical properties, e. g. , a high degree of adhesive and cohesive strength, is described.

Oxirane Primers For Smc Adhesives And Bonding Method Employing Same
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US Patent:

49160184, Apr 10, 1990
Filed:

Jul 21, 1986
Appl. No.:

6/887499
Inventors:

Anil B. Goel - Worthington OH
Joseph G. Holehouse - Columbus OH
Assignee:

Ashland Oil, Inc. - Ashland KY
International Classification:

B32B 2538
C09J 504
US Classification:

428414
Abstract:

A process for preparing novel composite structures by priming the surfaces of two or more substrates (such as SMC panels, etc. ) with an effective amount of an epoxy resin prior to adhering said surfaces together with an adhesive (such as a polyurethane adhesive) wherein said structures have improved high temperature (about 400. degree. F. ) tolerance is described.

Aromatic Isocyanate Preparation
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US Patent:

43538410, Oct 12, 1982
Filed:

Feb 19, 1982
Appl. No.:

6/350445
Inventors:

Jai H. Kyung - Dublin OH
Robert A. Grimm - Upper Arlington OH
Joseph G. Holehouse - Columbus OH
Assignee:

Ashland Oil, Inc. - Ashland KY
International Classification:

C07C11800
US Classification:

260453P
Abstract:

An aromatic isocyanate is formed directly from an aromatic hydrocarbon, nitric oxide and carbon monoxide by contacting a Group VII or Group VIII metal catalyst at a temperature between 350. degree. and 550. degree. C. with a feed stream of said reactants.

Thermoset Polymer Compositions
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US Patent:

47571152, Jul 12, 1988
Filed:

Nov 17, 1986
Appl. No.:

6/931496
Inventors:

Anil B. Goel - Worthington OH
Timothy A. Tufts - Columbus OH
Joseph G. Holehouse - Columbus OH
Assignee:

Ashland Oil, Inc. - Russell KY
International Classification:

C08G 1828
US Classification:

525440
Abstract:

Thermoset polymers are prepared by reacting an ethylenically unsaturated resin monomer and a bicyclic amide acetal with a polyisocyanate in the absence or presence of a vinyl monomer. Reaction rates are suitable for effecting RIM processing. The resultant polymers exhibit improved impact resistance. Further variation in physical properties can be achieved through the use of a diol chain extender for the polyisocyanate.

Joseph G Holehouse