Maurice E. Brooks - Great Neck NY Herbert Riegel - Palisades NJ Harvey D. Schindler - New York NY Morgan C. Sze - Upper Montclair NJ
Assignee:
The Lummus Company - Bloomfield NJ
International Classification:
C07C 6700
US Classification:
260488H
Abstract:
Process for coupling an alkane to either an alkane, alkene, aliphatic carboxylic acid, or aromatic hydrocarbon by effecting contacting thereof and a melt containing a multivalent metal halide in both its higher and lower valence state. In accordance with a preferred embodiment, the contacting is effected in the presence of an oxygen containing gas or the melt is previously contacted with an oxygen containing gas to produce the corresponding oxyhalide of the metal, whereby the reaction may be effected on a continuous basis.
1,2-Dichlorethane is dehydrochlorinated by direct contact with a molten salt including the higher and lower valent forms of a multivalent metal chloride and generally also the oxychloride of the metal with ethane being present to increase selectivity to vinyl chloride.
Morgan C. Sze - Upper Montclair NJ Harvey D. Schindler - Fairlawn NJ
Assignee:
The Lummus Company - Bloomfield NJ
International Classification:
C10G 2300
US Classification:
208251H
Abstract:
A metal containing hydrocarbon feedstock, such as a heavy residue, is contacted with hydrogen and a material characterized by low porosity, less than 0. 3 cc/gram; low surface area, less than 5 m. sup. 2 /g; high average pore diameter, greater than 1,000 Angstroms; and a high distribution of large pores, at least 40%, and preferably 50 to 80% of pores greater than 10,000 Angstroms. A preferred material is coke.
Harvey D. Schindler - Fair Lawn NJ Christine C. Albert - Peekskill NY Stephan J. DeCanio - Montgomery NY
Assignee:
Texaco Inc. - White Plains NY
International Classification:
B01D 3700
US Classification:
210770
Abstract:
A process for disposing of sanitary sewage sludge by producing a pumpable slurry of sewage sludge with or without solid carbonaceous fuel and burning said slurry as fuel in a partial oxidation gas generator, furnace, or boiler. The aqueous slurry of sewage sludge is concentrated by removing water by means of a conventional belt filter press, centrifuge, or hydroclone. The dewatered slurry of sewage sludge is heated by direct contact with steam while air and organic vapors are simultaneously removed, to reduce the pressure in the system; hydrothermally treated in two steps with indirect and direct heat exchange with steam; dewatered by flash evaporation and centrifuging; and burned with or without admixture with solid carbonaceous fuel in a partial oxidation gasifier, furnace, boiler, or incinerator to produce synthesis gas or a hot raw effluent gas stream. In a preferred embodiment, the effluent gas stream is cleaned and purified and non-contaminating ash and slag are separated. By this process, noxious sewage sludge may be disposed of without contaminating the environment.
A catalyst for hydrotreating of heavy feedstocks comprised of nickel and molybdenum, supported on alumina having a defined pore size distribution which has been calcined at a temperature of from 1150. degree. F. -1300. degree. F. Calcining of such catalyst at such temperatures is required in order to provide for effective use thereof as a hydrotreating catalyst for higher boiling feedstocks.
Maurice E. Brooks - Great Neck NY Herbert Riegel - Palisades NJ Harvey D. Schindler - New York NY Morgan C. Sze - Upper Montclair NJ
Assignee:
The Lummus Company - Bloomfield NJ
International Classification:
C07C 352 C07C 1510
US Classification:
260669R
Abstract:
Process for coupling an alkane to either an alkane, alkene, aliphatic carboxylic acid, or aromatic hydrocarbon by effecting contacting thereof and a melt containing a multivalent metal halide in both its higher and lower valance state. In accordance with a preferred embodiment, the contacting is effected in the presence of an oxygen containing gas or the melt is previously contacted with an oxygen containing gas to produce the corresponding oxyhalide of the metal, whereby the reaction may be effected on a continuous basis.
Harvey D. Schindler - Fair Lawn NJ James M. Chen - Edison NJ
Assignee:
Lummus Crest, Inc. - Bloomfield NJ
International Classification:
C10G 100
US Classification:
208409
Abstract:
Sub-bituminous coal is directly liquefied in two stages by use of a liquefaction solvent containing insoluble material as well as 850. degree. F. + material and 850. degree. F. - material derived from the second stage, and controlled temperature and conversion in the second stage. The process is in hydrogen balance.
Stripping Ammonia From Liquid Effluent Of A Hydrodenitrification Process
Morgan C. Sze - Upper Montclair NJ Harvey D. Schindler - Fairlawn NJ Anthony Fanelli - Rockaway NJ
Assignee:
The Lummus Company - Bloomfield NJ
International Classification:
C10G 2302
US Classification:
208254H
Abstract:
A nitrogen containing feedstock is hydrodenitrified by passing the feed through at least two hydrodenitrification zones, with ammonia produced in the hydrodenitrification being purged from the system prior to the last hydrodenitrification zone to maintain a low ammonia partial pressure in the last hydrodenitrification zone. The ammonia is preferably purged by stripping ammonia from the liquid portion of the effluent withdrawn from the next to last hydrodenitrification zone. Improved denitrification is obtained by maintaining a low ammonia partial pressure in the last hydrodenitrification zone.