- Santa Clara CA, US Sergey D. LOPATIN - Morgan Hill CA, US Eric H. LIU - Los Altos CA, US Ajey M. JOSHI - San Jose CA, US Guo AI - Guangdong, CN Zhihui WANG - Fremont CA, US Hui ZHAO - Boston MA, US Donghai WANG - State College PA, US
A simple solution processing method is developed to achieve uniform and scalable stabilized lithium metal powder coating on Li-ion negative electrode. A solvent and binder system for stabilized lithium metal powder coating is developed, including the selection of solvent, polymer binder and enhancement of polymer concentration. The enhanced binder solution is 1% concentration of polymer binder in xylene, and the polymer binder is chosen as the mixture of poly(styrene-co-butadiene) rubber (SBR) and polystyrene (PS). Long-sustained, uniformly dispersed stabilized lithium metal powder suspension can be achieved with the enhanced binder solution. A uniform stabilized lithium metal powder coating can be achieved with simple doctor blade coating method and the resulting stabilized lithium metal powder coating can firmly glued on the anode surface. With the prelithiation of negative electrode by stabilized lithium metal powder, improvements in electrochemical performances are demonstrated in both graphite/NMC and SiO/NMC full-cell.
Anode For Lithium Batteries, Lithium Battery And Method For Preparing Anode For Lithium Batteries
In forming an anode by using metallic lithium as the anode active material, the present invention provides an anode for lithium batteries which can be produced with high productivity and in which dendrite generation is prevented, so that high safety can be secured. The anode for lithium batteries according to the present invention comprises a structure, comprising a conductive material layer in which carbon nanotubes are anchored, with a part of the carbon nanotube extending from at least one face of the surfaces of the conductive material layer, and a deposited layer formed by depositing metallic lithium on the carbon nanotubes in the structure.
Silicon Oxide (Sio) Anode Enabled By A Conductive Polymer Binder And Performance Enhancement By Stabilized Lithium Metal Power (Slmp)
Silicon alloys have the highest specific capacity when used as anode material for lithium-ion batteries, however, the drastic volume change inherent in their use causes formidable challenges toward achieving stable cycling performance. Large quantities of binders and conductive additives are typically necessary to maintain good cell performance. In one embodiment of the invention, only 2% (by weight) functional conductive polymer binder without any conductive additives was successfully used with a micron-size silicon monoxide (SiO) anode material, demonstrating stable and high gravimetric capacity (>1000 mAh/g) for 500 cycles and more than 90% capacity retention. Prelithiation of this anode using stabilized lithium metal powder (SLMP) improves the first cycle Coulombic efficiency of a SiO/NMC full cell from 48% to 90%. This combination enables good capacity retention of more than 80% after 100 cycles at C/3 in a lithium-ion full cell.
Instrumentation To Dry-Deliver Slmp Particles To The Lithium-Ion Electrode
Gao Liu - Piedmont CA, US Vince Battaglia - San Anselmo CA, US Zhihui Wang - Fremont CA, US
Assignee:
The Regents of the University of California - Oakland CA
International Classification:
H01M 4/04
US Classification:
100102
Abstract:
An embodiment of the invention describes an calendaring apparatus comprising a roller press comprising a first roller and a second roller, a static electricity generator, a motor drive system in communication with the first roller and the second roller to impart rotation to first roller and the second roller, wherein the static electricity generator imparts a static charge to a surface of the first roller, and a material holding tray for holding a material in communication with the first roller.
Zeptor Corporation Oct 2014 - Feb 2017
Project Leader
Microsoft Oct 2014 - Feb 2017
Senior Reliability Engineer
Lawrence Berkeley National Laboratory Jul 2012 - Oct 2014
Chemist Postdoc Fellow
Stony Brook University Jan 2010 - Jun 2012
Postdoctoral Associate
Stony Brook University Jun 2005 - Dec 2009
Graduate Research Assistant
Education:
Stony Brook University 2004 - 2009
Doctorates, Doctor of Philosophy
Peking University 2000 - 2003
Master of Science, Masters, Environmental Science
Peking University 1996 - 2000
Bachelors, Bachelor of Science, Chemistry
Skills:
Uv/Vis Materials Science Gc Ms Lithium Ion Batteries Organic Chemistry Ftir R&D Information Extraction Vacuum Differential Scanning Calorimetry Sem Tem Characterization Chemistry Gas Analysis Tga Analytical Chemistry Research Research and Development Uv/Vis Spectroscopy Trace Gas Extraction and Sample Preparation Trace Gas Analysis Spectroscopy
2012 to 2000 Chemist Postdoctoral FellowSUNY at Stony Brook Stony Brook, NY 2010 to 2012 Postdoctoral AssociateSUNY at Stony Brook Stony Brook, NY 2005 to 2009 Graduate Research AssistantBeijing Purkinje General Instrument Co. LTD
Aug 2003 to Jun 2004 R&D and marketing
Education:
SUNY at Stony Brook Stony Brook, NY Dec 2009 Ph.D. in Marine and Atmospheric SciencePeking University Jun 2003 M. S. in Environmental SciencePeking University Jun 2000 B. S. in Chemistry
Skills:
Various electrochemical and structural characterization techniques: galvanostatic testing, EIS, CV, XRD, DSC, TGA, SEM etc.Analytical chemistry instrument: GC-FID, GC-MS, GC-IRMS, Quadrupole MS, Licor CO2 Analyzer, Reduction Gas Detector, UV-VIS spectrophotometer, Atomic Absorption Spectrometer