William B. McCormack - Wilmington DE Charles A. Sandy - Wilmington DE
Assignee:
E. I. du pont de Nemours & Company - Wilmington DE
International Classification:
C07F 1500 C07F 1504 C07F 1506
US Classification:
44 63
Abstract:
Hexacoordinated transition metal compounds, useful as antiknocks, having the structure ##STR1## wherein M is a divalent metal selected from the group Mn, Fe, Co and Ni, L. sub. 1 and L. sub. 2 are the same or different chelate-forming. beta. -diketone groups having from 5 to 20 carbon atoms, one or both of L. sub. 1 and L. sub. 2 having at least one polyfluoroalkyl group, --CF. sub. 2 X, adjacent to the carbonyl group, X is selected from the group H, F, Cl, phenyl, C. sub. 1 -C. sub. 6 alkyl and C. sub. n F. sub. 2n Y, n is 1 to 6, Y is H, F, or Cl, L. sub. 3 is a ligand having the structure A-Z-B, wherein A and B are the same or different members of the group --NH. sub. 2, --NHR. sub. 5, --NR. sub. 5 R. sub. 6, OH, OR. sub. 5, SH, SR. sub. 5 and PR. sub. 5 R. sub. 6, R. sub. 5 and R. sub. 6 are the same or different members of the group C. sub. 1 to C. sub.
E. I. Du Pont de Nemours and Company - Wilmington DE
International Classification:
C07C 7912
US Classification:
568936
Abstract:
Para-nitrobenzotrichloride is prepared by chlorinating nitrotoluene using an activated carbon catalyst. The process can use various cocatalysts such as bromine, iodine, PCl. sub. 3, S. sub. 2 Cl. sub. 2, bromide salts, chloranil, air bubbles and phthalimide. The reaction is carried out at from 20. degree. C. , to 220. degree. C. , with from 150. degree. to 200. degree. C. being the preferred range and a pressure of 1 to 5 Atm.
Sep 2013 to 2000Merrimack College Beacon (Newspaper)
Sep 2012 to 2000 Staff WriterMerrimack College Beacon (Newspaper)
Sep 2012 to 2000 Peer TutorMcCormack Farms
Sep 2012 to 2000The Barn
Jun 2012 to 2000 Head DriverMcCormack Farms
Sep 2011 to 2000McCormack Farms
Sep 2011 to 2000McCormack Farms
Jun 2006 to 2000 Greenhouse/Field Operations Management ApprenticeBrafton, Inc
May 2014 to Nov 2014 News and Content WriterMcCormack Farms
Jan 2014 to May 2014 Editorial Intern
Education:
Monmouth University West Long Branch, NJ Sep 2014 to 2000 Masters in HistoryMerrimack College North Andover North Andover, MA May 2014 Bachelor of Arts in History and Philosophy