Wayne A. Bowman - Walworth NY Leslie Shuttleworth - Webster NY Helmut Weber - Webster NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
B41M 5035 B41M 538
US Classification:
503227
Abstract:
A thermal dye transfer assemblage comprising: (a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being a cationic dye or a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N--H group which is part of a conjugated system, and (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the dye image-receiving layer, the dye image-receiving layer comprising a polyester ionomer comprising a polyester backbone containing units of a sulfonic acid or a sulfonimide or their salts, with the proviso that when the dye is a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N--H group which is part of a conjugated system, the dye image-receiving layer comprises a polyester ionomer comprising a polyester backbone containing units of a sulfonic acid or a sulfonimide.
Thermal Dye Transfer System With Low Tg Polymeric Receiver Mixture
Wayne A. Bowman - Walworth NY Daniel J. Harrison - Pittsford NY Karen M. Kosydar - Penfield NY Teh-Ming Kung - Rochester NY Kristine B. Lawrence - Rochester NY William H. Simpson - Pittsford NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
B41M 5035 B41M 538
US Classification:
503227
Abstract:
A thermal dye transfer assemblage comprising: (a) a dye-donor dement comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N--H group which is part of a conjugated system, and (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer, the polymeric dye image-receiving layer comprising a mixture of an organic polymeric or oligomeric acid which is capable of reprotonating the deprotonated cationic dye and a polymer having a Tg of less than about 19. degree. C. and having no or only slight acidity.
Wayne A. Bowman - Walworth NY Charles P. Hagmaier - Rochester NY Frank D. Manioci - Henrietta NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 826 G03C 725 G03C 724
US Classification:
430199
Abstract:
Dye imbibition printing blanks are disclosed comprising a support bearing a layer comprising a cationic mordant, a hydrophilic colloid and a plasticizer polymer, wherein the plasticizer polymer is a latex polymer having a glass transition temperature below about 30. degree. C. comprising from about 2 to 20 wt % of units having a quaternary ammonium group. In a preferred embodiment, the latex polymer comprises a vinyl co-polymer addition product of from about 50 to 98 weight percent of acrylic or methacrylic ester units, 0 to 48 weight percent of vinyl benzene units and 2 to 20 weight percent of the quaternary ammonium group containing unit. This latex provides a dye imbibition printing blank substantially free of haze and brittleness.
Sulfonate-Containing Polymeric Binder In Dye-Donor Element For Thermal Dye Transfer Systems
Wayne A. Bowman - Walworth NY Karen M. Kosydar - Penfield NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
B41M 5035 B41M 526
US Classification:
430200
Abstract:
This invention relates to a dye-donor element for thermal dye transfer comprising a support having thereon a dye layer comprising an image dye dispersed in a binder, wherein the binder comprises a water-dispersible vinyl copolymer having a glass transition temperature below about 54. degree. C. and having the formula: ##STR1## wherein: R. sup. 1 and R. sup. 2 each independently represents hydrogen or methyl; D represents a substituted or unsubstituted phenyl group; or --COOR. sup. 3, where R. sup. 3 represents a substituted or unsubstituted alkyl group of 1 to about 6 carbon atoms, a substituted or unsubstituted cycloalkyl group of about 5 to about 8 carbon atoms, or an organic group containing ethylenic unsaturation; E represents --C. sub. 6 H. sub. 4 --; --CONHR. sup. 4 --; or --COOR. sup.
Aqueous Coating Compositions For Antistat Layers Having Print Retaining Qualities
Wayne A. Bowman - Walworth NY Mario D. DeLaura - Rochester NY Norman S. Edgett - Rochester NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
C08J 510 C08K 334 C08L 3312
US Classification:
524493
Abstract:
An aqueous coating composition for applying a print retaining antistatic layer consisting essentially of an aluminum modified colloidal silica and an antistatic agent in a binder polymer, the binder polymer consisting essentially of an addition product of from about 30 to 78 mol % of an alkyl methacrylate wherein the alkyl group has from 3 to 8 carbon atoms, from about 2 to about 10 mol % of an alkali metal salt of an ethylenically unsaturated sulfonic acid and from 20 to about 65 mol % of a vinyl benzene, the polymer having a glass transition point of from 30. degree. to 65. degree. C.
Dye Imbibition Printing Blanks With Antistatic Layer
Wayne Arthur Bowman - Walworth NY Charles Peter Hagmaier - Rochester NY Frank Dean Manioci - Henrietta NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 185 G03C 852 B41N 100
US Classification:
430 14
Abstract:
Dye imbibition printing blanks are disclosed comprising a support bearing on one side thereof a dye-receiving layer comprising a cationic mordant, and further comprising an antistatic layer substantially free of cationic polymers. The antistatic layer is preferably provided on the opposite side of the support relative to the dye-receiving layer. Such antistatic layer provides improved antistatic properties which enable high manufacturing and processing speeds without adversely affecting printed image qualities.
Marianne Yarmey - Amhurst MA Wayne Arthur Bowman - Walworth NY Stephen Joseph Kozak - Webster NY Gary Francis Mitchell - Rochester NY Glenn Thomas Pearce - Fairport NY Melvin David Sterman - Pittsford NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 1015 G03C 138
US Classification:
430631
Abstract:
The invention is generally accomplished by providing a photographic element and a process of its formation wherein a gelatin silver halide emulsion is provided with a thickener comprising a copolymer of the structure wherein A comprises about 10 to about 20 parts by weight of said copolymer, and B comprises about 80 to about 90 parts by weight of said copolymer. It is particularly preferred that the copolymer be provided in a hardener layer to minimize the amount of gelatin needed and thus reduce the reaction of hardener with gelatin. The invention finds a preferred use in curtain coating wherein there is a greater need for high viscosity materials, particularly at the bottom of a group of layers in order to minimize distortions of the layers as they are applied in the curtain coating process.
Preparation Of Thin Tabular Grain Silver Halide Emulsions Using Synthetic Polymeric Peptizers
Wayne A. Bowman - Walworth NY Roger A. Weiss - Webster NY Gerald W. Klein - Issaquah NY John E. Keevert - Rochester NY Shane C. Weber - Rochester NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 1015 G03C 1005 G03C 104
US Classification:
430569
Abstract:
A process for preparing a thin tabular grain silver halide emulsion comprised of silver halide grains which have a halide content of at least 50 mole percent bromide, wherein tabular grains of less than 0. 15 micrometers in thickness and having an aspect ratio of greater than 8 account for greater than 50 percent of the total grain projected area, comprises the steps of nucleating the silver halide grains with a gelatino-peptizer or with the use of certain synthetic polymers that serve as effective nucleation peptizers and then growing the silver halide grains with the use of either a gelatino-peptizer or certain synthetic polymers that serve as effective growth peptizers.
Wayne Bowman (1963-1967), Gary Hunt (1961-1965), Brenda Lamtman (1978-1982), James Richardson (1974-1978), Tyler Skeens (1999-2003), Alexander Coulter (1955-1959)