Leo Kim - Houston TX Timm E. Paxson - Houston TX Sunny C. Tang - Houston TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
B01J 3108 B01J 3110
US Classification:
252431C
Abstract:
A composition comprising an ion exchange resin and an organic linking compound having at least one resin-compatible moiety ionically bound to said resin and further having at least one metal complexible moiety selected from the group consisting of trivalent nitrogen, trivalent phosphorus, trivalent arsenic, trivalent bismuth and trivalent antimony complexed to a metal selected from Group IVB, VB, VIB, VIIB, VIII and IB metals, said composition being useful in heterogeneous catalysis.
Hydroformylation Process Using Resin-Ligand-Metal Catalyst
Leo Kim - Houston TX Timm E. Paxson - Houston TX Sunny C. Tang - Katy TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
C07C 4550 C07C 2722
US Classification:
568454
Abstract:
The hydroformylation of olefinic hydrocarbons is effected by treating the hydrocarbon with hydrogen and carbon monoxide in the presence of a catalyst comprising an ion exchange resin, a metal selected from the group consisting of cobalt, ruthenium, palladium, platinium, and rhodium bound to said resin and an organic linking compound which has at least one moiety which is ionically bonded to said resin and which further has at least one moiety which is coordinately bonded to said metal.
Leo Kim - Houston TX Timm E. Paxson - Houston TX Sunny C. Tang - Houston TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
C07C 4500
US Classification:
260600R
Abstract:
Meta-phenoxytoluene is oxidized by selenium dioxide in the presence of a dehydration agent to yield meta-phenoxy-benzaldehyde containing less than 250 ppm dissolved selenium at a selectivity based on the toluene of about 90% or better.
Timm E. Paxson - Houston TX Leo Kim - Houston TX Andre B. Van Aken - Amsterdam, NL
Assignee:
Shell Oil Company - Houston TX
International Classification:
C07C 4106
US Classification:
568678
Abstract:
An improved process for preparing. beta. -(sec-alkoxy) ethanol which comprises reacting an olefin with ethylene glycol in the presence of a sulfuric acid or benzenesulfonic acid catalyst and sufficient sulfolane or alkyl-substituted sulfolane solvent to provide a one phase reaction medium, extracting the reaction products with an alkane and recovering the. beta. -(sec-alkoxy) ethanol product from the alkane extract.
Leo Kim - Modesto CA Timm E. Paxson - Houston TX Sunny C. Tang - Katy TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
C07C 502 C07C 503
US Classification:
585277
Abstract:
A process for the hydrogenation of unsaturated hydrocarbons comprising contacting said unsaturated hydrocarbons, with hydrogen, at temperatures ranging from about 40. degree. C. to about 160. degree. C. , and pressures ranging from about 100 psi to about 3000 psi, with a catalyst comprising an ion exchange resin and an organic linking compound having at least one resin compatible moiety ionically bound to said resin and further having at least one metal complexible moiety selected from the group consisting of trivalent nitrogen, trivalent phosporous, trivalent arsenic, trivalent bismuth and trivalent antimony complexed to a metal selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum.
Marion F. Hawthorne - Brentwood CA Timm E. Paxson - Houston TX
Assignee:
The United States of America as represented by the Secretary of the Navy - Washington DC
International Classification:
B01J 3112 C07F 1500
US Classification:
252431P
Abstract:
A family of stable hydrido-rhodium and iridium carboranes are described which are effective catalysts for the homogeneous hydrogenation, isomerization and hydroformylation of olefins and the hydrosilylation of ketones.
Leo Kim - Modesto CA Timm E. Paxson - Houston TX Sunny C. Tang - Katy TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
C07C 600
US Classification:
585645
Abstract:
The disproportionation of olefins is effected by contacting the olefin with an activator and a catalyst comprising an ion exchange resin and an organic linking compound having at least one resin-compatible moiety ionically bonded to said resin and further having at least one metal complexible moiety selected from the group consisting of trivalent nitrogen, trivalent phosphorus, trivalent arsenic, trivalent bismuth and trivalent antimony complexed to a metal selected from the group consisting of molybdenum, tungsten and rhenium.
Hydroformylation Process Using Resin-Ligand-Metal Catalyst
Leo Kim - Houston TX Timm E. Paxson - Houston TX Sunny C. Tang - Katy TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
C07C 4550 C07C 2722
US Classification:
568454
Abstract:
The hydroformylation of olefinic hydrocarbons is effected by treating the hydrocarbon with hydrogen and carbon monoxide in the presence of a catalyst comprising an ion exchange resin and an organic linking compound having at least one resin-compatible moiety ionically bonded to said resin and further having at least one metal complexible moiety selected from the group consisting of cobalt, ruthenium, palladium, platinum and rhodium.