Nan L. Yang - Staten Island NY Andrew Auerbach - Livingston NJ Rose Pesce - College Point NY Jerry A. Broussard - Summit NJ James L. Paul - Summit NJ
Assignee:
Hoechst Celanese Corporation - Somerville NJ
International Classification:
C08G 210
US Classification:
528230
Abstract:
Cationic polymerization of trioxane and a mixture of ester derivatives of. alpha. ,. alpha. - and. alpha. ,. beta. -isomers of glycerol formal yields acetal terpolymers having pendant functional groups (i. e. , ester groups, or hydroxyl groups obtained by hydrolyzing ester groups, pendent from the polymer's backbone). The glycerol formal monomers employed in this invention may include functional groups selected from ester moieties which are protected from, and thus survive, the polymerization process with trioxane. These groups may then be present as functional reactive sites for the subsequent synthesis of block polymers and/or to chemically bind modifiers to the acetal terpolymer backbone, for example.
Acetal Copolymers With Backbone Bromo Functional Groups
Andrew Auerbach - Livingston NJ James L. Paul - Summit NJ Rose Pesce - College Point NY Shian S. Wang - New York NY
Assignee:
Hoechst Celanese Corp. - Chatham NJ
International Classification:
C08G 400
US Classification:
528249
Abstract:
The invention concerns a method for producing an acetal copolymer containing backbone bromo-functional groups comprising copolymerizing trioxane with 5,6,-dibromo-1,3-dioxepene. The invention also concerns methods of modifying acetal copolymers containing bromo-functional groups and the copolymers produced by the methods of the invention.
(Iodo-Urea And Iodo-Isocyano) Dioxepane Trioxane Copolymers
Andrew Auerbach - Livingston NJ James L. Paul - Summit NJ Rose Pesce - College Point NY
Assignee:
Hoechst Celanese Corporation - Chatham NJ
International Classification:
C08G 224 C08G 226 C08G 230
US Classification:
528249
Abstract:
Iodoisocyano, iodourea and oxazole modified 1,3 dioxep-5-ene ring monomers are synthesized and used in copolymerization reactions with trioxane to produce acetal copolymers with backbone functional groups. The invention also concerns processes for the production of acetal copolymers containing iodourea and oxazole functional groups from acetal copolymers with backbone double bonds.
Acetal Copolymers With Backbone Double Bonds And Graft Copolymers Thereof
Andrew Auerbach - Livingston NJ James L. Paul - Summit NJ Rose Pesce - College Point NY Shian S. Wang - New York NY
Assignee:
Hoechst Celanese Corporation - Chatham NJ
International Classification:
C08F28306 C08G 224
US Classification:
525412
Abstract:
Acetal copolymers of trioxane and 1,3-dioxep-5-ene having a high degree of crystallinity and specific mole percent incorporations of 1,3-dioxep-5-ene are synthesized. The invention also provides a process for producing highly crystalline acetal copolymers by copolymerizing triozane and 1,3-dioxep-5-ene and precipitating the copolymer product from solution. The copolymers show much improved stability against halogen degradation.
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