Abstract:
A method of casting liquid compositions in elastomeric molds wherein the casting composition has a reaction temperature below about 235. degree. F comprising: A. introducing an organic solvent soluble polyol, a liquid polyisocyanate and a basic curing catalyst having a pK. sub. b value from between 7 and about 11 into an open elastomeric mold, B. controlling the ratio of polyol to polyisocyanate and the concentration of the curing catalyst and casting the resin such that the cured resin is: substantially free from entrapped air at the mold surface, free from foaming, has a cast time of generally less than about 15 minutes, has a tensile strength of at least about 2500 psi, C. removing the cast resin from the mold shortly after the composition is cast thereby providing unexpected prolonged mold life. The resin undergoes substantially no change in volume from the liquid to the cured state.