In accordance with the present invention, a catalyst is described which comprises at least one metal selected from the group consisting of copper, zinc, iron, tungsten, molybdenum, and chromium distributed over a catalyst support comprising a material containing at least one of silicon, titanium, zirconium, magnesium, aluminum, and activated carbon. The catalyst is used to remove phosgene from a contaminated gas stream and/or reduce or eliminate phosgene from an effluent of a previously treated gas stream. At least one metal in the catalyst of the present invention is preferably present in an amount from about 0. 001 wt % to about 15 wt %. When more than one metal is present, the combined metals preferably do not exceed 20 wt %. Catalysts in accordance with the present invention may be used as Photocatalysts. Processes for using the catalysts and Photocatalysts of the present invention are also described.
Method, Catalyst, And Photocatalyst For The Destruction Of Phosgene
In accordance with the present invention, a catalyst is described which comprises at least one metal selected from the group consisting of copper, zinc, iron, tungsten, molybdenum, and chromium distributed over a catalyst support comprising a material containing at least one of silicon, titanium, zirconium, magnesium, aluminum, and activated carbon. The catalyst is used to remove phosgene from a contaminated gas stream and/or reduce or eliminate phosgene from an effluent of a previously treated gas stream. At least one metal in the catalyst of the present invention is preferably present in an amount from about 0. 001 wt % to about 15 wt %. When more than one metal is present, the combined metals preferably do not exceed 20 wt %. Catalysts in accordance with the present invention may be used as photocatalysts. Processes for using the catalysts and photocatalysts of the present invention are also described.
James R. Kittrell - Amherst MA Donald L. Herman - Yardley PA
Assignee:
New England Power Service Company - Westborough MA Northeast Utilities Service Company - Newington CT
International Classification:
B01J 800 C01B 2100
US Classification:
423239
Abstract:
Base metal catalysts are pretreated with selenium, sulfur or sulfur compounds. Subsequently, a gaseous stream comprising nitric oxide, oxygen and ammonia is passed over the pretreated catalysts. The nitric oxide is reduced to nitrogen and no nitrous oxide is formed.
Process For The Preparation Of Copolymers Of Maleic Anhydride And Alkyl Vinyl Ether
James R. Kittrell - Amherst MA Charles W. Quinlan - Amherst MA
Assignee:
KSE Inc. - Sunderland MA
International Classification:
C08F 200
US Classification:
526 77
Abstract:
A copolymer of maleic anhydride and an alkyl vinyl ether is prepared with substantially reduced benzene content by first contacting the alkyl vinyl ether with activated charcoal and then reacting together the charcoal treated alkyl vinyl ether and maleic anhydride in the presence of a free radical initiator.
Two Stage Process And Catalyst For Photocatalytic Conversion Of Contaminants
James R. Kittrell - Amherst MA David A. Gerrish - Amherst MA
Assignee:
KSE, Inc. - Sunderland MA
International Classification:
C07B 6300
US Classification:
2041582
Abstract:
A process and apparatus for the oxidation of gaseous contaminants for the control of air pollution, comprises a two stage process comprising a photolytic stage followed by a photocatalytic stage.
Process For The Catalytic Reduction Of Nitric Oxide
James R. Kittrell - Amherst MA Donald L. Herman - Yardley PA
Assignee:
New England Power Service Company - Westborough MA Northern Utilities Service Company - Newington CT
International Classification:
B01J 800 C01B 2100
US Classification:
423239
Abstract:
Base metal catalysts are pretreated with selenium, sulfur or sulfur compounds. Subsequently, a gaseous stream comprising nitric oxide, oxygen and ammonia is passed over the pretreated catalysts. The nitric oxide is reduced to nitrogen and no nitrous oxide is formed.
James R. Kittrell - Amherst MA Donald L. Herman - Coventry RI
Assignee:
Northeast Utilities Service Company - Hartford CT New England Power Service Company - Westborough MA
International Classification:
B01J 800 C01B 2100
US Classification:
423239
Abstract:
A process for reducing nitric oxide with ammonia in the presence of a copper-exchanged mordenite catalyst at a temperature between about 300. degree. F. and 800. degree. F.