Douglas A. Buchanan - Cortlandt Manor NY Evgeni P. Gousev - Mahopac NY Carol J. Heenan - LaGrangeville NY Wade J. Hodge - Bolton VT Steven M. Shank - Jericho VT Patrick R. Varekamp - Croton on Hudson NY
Assignee:
International Business Machines Corporation - Armonk NY
International Classification:
H01L 2131
US Classification:
438774, 438769, 438770, 438773
Abstract:
An apparatus and method of forming an oxynitride insulating layer on a substrate performed by putting the substrate at a first temperature within the main chamber of a furnace, exposing the substrate to a nitrogen containing gas at a second temperature which is higher than the first temperature, and growing the oxynitride layer on the substrate within the main chamber in the presence of post-combusted gases. The higher temperature nitrogen containing gases are combusted in a chamber outside the main chamber. The higher temperature is in the range of 800 to 1200Â C. , and preferably 950Â C. In a second embodiment, distributed N O gas injectors within the main chamber deliver the nitrogen containing gas. The nitrogen containing gas is pre-heated outside the chamber. The nitrogen containing gas is then delivered to a gas manifold that splits the gas flow and directs the gas to a number of gas injectors, preferably two to four injectors within the main process tube.
Methods For Forming Metal Oxide Layers With Enhanced Purity
Alessandro Cesare Callegari - Yorktown Heights NY Fuad Elias Doany - Katonah NY Evgeni Petrovich Gousev - Mahopac NY Theodore Harold Zabel - Yorktown Heights NY
Assignee:
International Business Machines Corporation - Armonk NY
International Classification:
H01L 2131
US Classification:
438785, 438771, 438795
Abstract:
Within: (1) a method for purifying a metal oxide layer; and (2) a method for forming with enhanced purity a metal oxide layer, there is employed an irradiation of either: (1) a metal oxide layer; or (2) a substrate in the presence of at least one of an oxidant and a metal source material, such as to either: (1) reduce a concentration of a contaminant material within a metal oxide base material from which is formed a metal oxide layer; or (2) inhibit in a first instance formation of a contaminant material within a metal oxide layer. The metal oxide layer having incorporated therein the reduced concentration of contaminant material is particularly useful as a capacitive dielectric layer within a capacitive device within a microelectronic fabrication.
Apparatus And Method For Forming An Oxynitride Insulating Layer On A Semiconductor Wafer
Douglas A. Buchanan - Cortlandt Manor NY Evgeni P. Gousev - Yorktown Heights NY Carol J. Heenan - LaGrangeville NY Wade J. Hodge - Bolton VT Steven M. Shank - Jericho VT Patrick R. Varekamp - Croton on Hudson NY
Assignee:
International Business Machines Corporation - Armonk NY
International Classification:
H01L 2131
US Classification:
118725, 118715, 118719, 438773, 438774
Abstract:
An apparatus and method of forming an oxynitride insulating layer on a substrate performed by putting the substrate at a first temperature within the main chamber of a furnace, exposing the substrate to a nitrogen containing gas at a second temperature which is higher than the first temperature, and growing the oxynitride layer on the substrate within the main chamber in the presence of post-combusted gases. The higher temperature nitrogen containing gases are combusted in a chamber outside the main chamber. The higher temperature is in the range of 800 to 1200Â C. , and preferably 950Â C. In a second embodiment, distributed N O gas injectors within the main chamber deliver the nitrogen containing gas. The nitrogen containing gas is pre-heated outside the chamber. The nitrogen containing gas is then delivered to a gas manifold that splits the gas flow and directs the gas to a number of gas injectors, preferably two to four injectors within the main process tube.
Interfacial Oxidation Process For High-K Gate Dielectric Process Integration
Arne W. Ballantine - Round Lake NY Douglas A. Buchanan - Cortlandt Manor NY Eduard A. Cartier - New York NY Kevin K. Chan - Staten Island NY Matthew W. Copel - Yorktown Heights NY Christopher P. DEmic - Ossining NY Evgeni P. Gousev - Mahopac NY Fenton Read McFeely - Ossining NY Joseph S. Newbury - Tarrytown NY Patrick R. Varekamp - Croton-on-Hudson NY Theodore H. Zabel - Yorktown Heights NY
Assignee:
International Business Machines Corporation - Armonk NY
International Classification:
H01L 21469
US Classification:
438770
Abstract:
A method for integrating a high-k material into CMOS processing schemes is provided. The method includes forming an interfacial oxide, oxynitride and/or nitride layer on a device region of a semiconductor substrate, said interfacial layer having a thickness of less than 10 ; and (b) forming a high-k dielectric material on said interfacial oxide, oxynitride and/or, nitride layer, said high-k dielectric having a dielectric constant, k, of greater than 8.
High-Dielectric Constant Insulators For Feol Capacitors
Arne W. Ballantine - Round Lake NY Douglas A. Buchanan - Cortlandt Manor NY Eduard A. Cartier - Leuven, BE Douglas D. Coolbaugh - Essex Junction VT Evgeni P. Gousev - Mahopac NY
Assignee:
International Business Machines Corporation - Armonk NY
International Classification:
H01L 2100
US Classification:
438239, 438392, 438253, 257296, 257300
Abstract:
Methods of forming front-end-of the line (FEOL) capacitors such as polysilicon-polysilicon capacitors and metal-insulator-silicon capacitors are provided that are capable of incorporating a high-dielectric constant (k of greater than about 8) into the capacitor structure. The inventive methods provide high capacitance/area devices with low series resistance of the top and bottom electrodes for high frequency responses. The inventive methods provide a significant reduction in chip size, especially in analog and mixed-signal applications where large areas of capacitance are used.
Thermally Stable Poly-Si/High Dielectric Constant Material Interfaces
Alessandro C. Callegari - Yorktown Heights NY Evgeni Gousev - Mahopac NY Michael A. Gribelyuk - Poughquag NY Paul C. Jamison - Hopewell Junction NY Dianne L. Lacey - Mahopac NY
Assignee:
International Business Machines Corporation - Armonk NY
The present invention provides a method of fabricating a thermally stable polysilicon/high-k dielectric film stack utilizing a deposition method wherein Si-containing precursor gas which includes silicon and hydrogen is diluted with an inert gas such as He so as to significantly reduce the hydrogen content in the resultant polysilicon film. Semiconductor structures such as field effect transistors (FETs) and capacitors which include at least the thermally stable polysilicon/high-k dielectric film stack are also provided herein.
Method For Forming Heavy Nitrogen-Doped Ultra Thin Oxynitride Gate Dielectrics
Evgeni Gousev - Mahopac NY Atul C. Ajmera - Wappingers Falls NY Christopher P. DEmic - Ossining NY
Assignee:
International Business Machines Corporation - Armonk NY
International Classification:
H01L 21469
US Classification:
438786, 438787, 438788, 438791
Abstract:
A method for forming an ultra thin gate dielectric for an integrated circuit device is disclosed. In an exemplary embodiment of the invention, the method includes forming an initial nitride layer upon a substrate by rapidly heating the substrate in the presence of an ammonia (NH ) gas, and then re-oxidizing the initial nitride layer by rapidly heating the initial nitride layer in the presence of a nitric oxide (NO) gas, thereby forming an oxynitride layer. The oxynitride layer has a nitrogen concentration therein of at about 1. 0Ã10 atoms/cm to about 6. 0Ã10 atoms/cm , and has a thickness which may be controlled within a sub 10 range.
Apparatus And Method For Forming An Oxynitride Insulating Layer On A Semiconductor Wafer
Douglas A. Buchanan - Cortlandt Manor NY, US Evgeni P. Gousev - Mahopac NY, US Carol J. Heenan - LaGrangeville NY, US Wade J. Hodge - Bolton VT, US Steven M. Shank - Jericho VT, US Patrick R. Varekamp - Croton on Hudson NY, US
Assignee:
International Business Machines Corporation - Armonk NY
International Classification:
H01L021/31 H01L021/469
US Classification:
438773, 438774, 438775
Abstract:
An apparatus and method of forming an oxynitride insulating layer on a substrate performed by putting the substrate at a first temperature within the main chamber of a furnace, exposing the substrate to a nitrogen containing gas at a second temperature which is higher than the first temperature, and growing the oxynitride layer on the substrate within the main chamber in the presence of post-combusted gases. The higher temperature nitrogen containing gases are combusted in a chamber outside the main chamber. The higher temperature is in the range of 800 to 1200 C. , and preferably 950 C. In a second embodiment, distributed NO gas injectors within the main chamber deliver the nitrogen containing gas. The nitrogen containing gas is pre-heated outside the chamber. The nitrogen containing gas is then delivered to a gas manifold that splits the gas flow and directs the gas to a number of gas injectors, preferably two to four injectors within the main process tube.